Kinetic modelling of the thermal decomposition of ettringite into metaettringite

Jérémie Pourchez 1, 2, 3, * Françoise Valdivieso 1, 3, 4 Philippe Grosseau 1, 2, 3 Alexandre Govin 1, 2, 3 Bernard Guilhot 1, 2, 3
* Corresponding author
1 SPIN-ENSMSE - Centre Sciences des Processus Industriels et Naturels
2 P2MC-ENSMSE - Département Poudres et Matériaux Multi-Composants
3 LPMG-EMSE - Laboratoire des Procédés en Milieux Granulaires
4 ProcESS-ENSMSE - Département Procédés et évolution des systèmes avec solides
Abstract : Despite recent insights into thermal stability of ettringite and structural changes during decomposition, a lack of knowledge on nucleation and growth mechanisms of metaettringite remained. Therefore, a better understanding of the kinetic modelling of this heterogeneous reaction was proposed. Thanks to an experimental approach allowing to check the validity of kinetic assumptions (rate-determining step, expression of the rate as d alpha/dt=k f(alpha)...), a good agreement was found between the calculated and experimental alpha vs. t and d alpha/dt vs. t kinetic curves. The reaction area of the region in which the rate-limiting step occurs was also elucidated. Finally, we demonstrated that the rate-limiting step of the growth process follows an Arrhenius law in non-isothermal conditions.
keyword : Ettringite Metaettringite Thermal decomposition Kinetic modelling
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Jérémie Pourchez, Françoise Valdivieso, Philippe Grosseau, Alexandre Govin, Bernard Guilhot. Kinetic modelling of the thermal decomposition of ettringite into metaettringite. Cement and Concrete Research, Elsevier, 2006, 36 (11), pp.2054-2060. ⟨10.1016/j.cemconres.2006.06.007⟩. ⟨emse-00449727⟩

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