Development of Single Chamber Solid Oxide Fuel Cells (SCFC)

Abstract : Single Chamber Solid Oxide Fuel Cells (SCFC) have been prepared using an electrolyte as support (Ce0.9Gd0.1O1.95 named GDC). Anode (Ni-GDC) and different cathodes (Sm0.5Sr0.5CoO3 (SSC), Ba0.5Sr0.5Co0.2Fe0.8O3 (BSCF) and La0.8Sr0.2MnO3 (LSM)) were placed on the same side of the electrolyte. All the electrodes were deposited using screen-printing technology. A gold collector was also deposited on the cathode to decrease the over-potential. The different materials and fuel cell devices were tested under propane/air mixture, after a preliminary treatment under hydrogen to reduce the as-deposited nickel oxide anode. The results show that SSC and BSCF cathodes are not stable in these conditions, leading to a very low open circuit voltage (OCV) of 150 mV. Although LSM material is not the more adequate cathode regarding its high catalytic activity towards hydrocarbon conversion, it has a better chemical stability than SSC and BSCF. Ni-GDC-LSM SCFC devices were elaborated and tested; an OCV of nearly 750 mV could be obtained with maximum power densities around 20 mW cm–2 at 620 °C, under air–propane mixture with C3H8/O2 ratio equal to 0.53.
Type de document :
Article dans une revue
Fuel Cells, Wiley-VCH Verlag, 2010, 10 (4), pp.683-692. 〈10.1002/fuce.200900146〉
Liste complète des métadonnées

Littérature citée [6 références]  Voir  Masquer  Télécharger

https://hal-emse.ccsd.cnrs.fr/emse-00517389
Contributeur : Andrée-Aimée Toucas <>
Soumis le : mardi 21 septembre 2010 - 17:13:43
Dernière modification le : jeudi 11 janvier 2018 - 06:21:23

Fichier

JPV-FC-10-4-683-original.pdf
Fichiers produits par l'(les) auteur(s)

Identifiants

Citation

Jean-Paul Viricelle, Sorina-Nicoleta Udroiu, Geoffroy Gadacz, Michèle Pijolat, Christophe Pijolat. Development of Single Chamber Solid Oxide Fuel Cells (SCFC). Fuel Cells, Wiley-VCH Verlag, 2010, 10 (4), pp.683-692. 〈10.1002/fuce.200900146〉. 〈emse-00517389〉

Partager

Métriques

Consultations de la notice

181

Téléchargements de fichiers

181