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Influence of high temperature treatments under net oxidizing and reducing conditions on the oxygen storage and buffering properties of a Ce0.68Zr0.32O2 mixed oxide

Abstract : TPR, TPO, O2 pulses and magnetic balance experiments have been performed to study the effect of two different aging treatments, in oxidizing atmosphere and in reducing conditions, on the redox behavior of a Ce0.68Zr0.32O2 mixed oxide. It has been observed that, although the samples resulting from both treatments have similar textural properties, their redox behavior is significantly different. In particular, aging in H2 improves the oxygen storage capacity (OSC) at low temperatures by decreasing the temperature at which reduction takes place. Also, the oxygen buffering capacity (OBC) is enhanced after aging under reducing conditions. In addition, the study of the re-oxidation of the samples reveals that the rate of the O2 uptake increases if compared with the fresh sample or that aged in air. High resolution electron microscopy and Raman spectroscopy data have also been used to obtain information on the possible origin of such effects.
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https://hal-emse.ccsd.cnrs.fr/emse-00609996
Contributor : Andrée-Aimée Toucas <>
Submitted on : Wednesday, July 20, 2011 - 4:32:28 PM
Last modification on : Wednesday, June 24, 2020 - 4:18:29 PM

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Hilario Vidal, Serafin Bernal, Jan Kaspar, Michèle Pijolat, Vincent Perrichon, et al.. Influence of high temperature treatments under net oxidizing and reducing conditions on the oxygen storage and buffering properties of a Ce0.68Zr0.32O2 mixed oxide. Catalysis Today, Elsevier, 1999, 54 (1), pp.93-100. ⟨10.1016/S0920-5861(99)00171-6⟩. ⟨emse-00609996⟩

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