Abstract : A polysilazane precursor was studied from 500 to 1600°C by means of thermogravimetry and associated mass spectrometry. At 550°C, opposite influences of methane and hydrogen partial pressures on the weight loss were evidenced. At 1600°C, the amorphous solid crystallizes into silicon, silicon carbide and silicon nitride phases by producing carbon and silicon monoxides and nitrogen.
https://hal-emse.ccsd.cnrs.fr/emse-00610368
Contributeur : Andrée-Aimée Toucas
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Soumis le : jeudi 21 juillet 2011 - 16:40:54
Dernière modification le : mardi 23 octobre 2018 - 14:36:05
Marie Gabrielle Salvetti, Michèle Pijolat, Michel Soustelle. Pyrolysis of a polysilazane precursor to SiCN ceramics. Solid State Ionics, Elsevier, 1993, 63-65, pp.332-339. 〈10.1016/0167-2738(93)90125-M〉. 〈emse-00610368〉
