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In situ infrared spectroscopic study of uranium oxides during UO3 carboreduction

Florence Poncet 1, 2 Françoise Valdivieso 1, 2 Raymonde Gibert 1, 3 Michèle Pijolat 1, 2
1 SPIN-ENSMSE - Centre Sciences des Processus Industriels et Naturels
2 ProcESS-ENSMSE - Département Procédés et évolution des systèmes avec solides
3 P2MC-ENSMSE - Département Poudres et Matériaux Multi-Composants
Abstract : Carboreduction of UO3 has been studied by in situ infrared spectroscopy in order to detect the presence of carbon monoxide during the reduction. From thermogravimetry, the reaction was observed to occur in two steps: (i) Reduction of UO3 to U3O8 by carbon at 440°C and (ii) reduction at 590°C of U3O8 to UO23 by carbon. No carbon monoxide was observed during the reaction. Nevertheless, formation of carboxylate species is observed at temperature below 550°C with absorption bands at 1017 and 1300 cm-1.
Keywords : uranium oxides in situ infrared spectroscopy thermogravimetry UO3 carboreduction U3O8 UO2
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https://hal-emse.ccsd.cnrs.fr/emse-00614946
Contributor : Andrée-Aimée Toucas <>
Submitted on : Wednesday, August 17, 2011 - 3:26:40 PM
Last modification on : Wednesday, June 24, 2020 - 4:18:29 PM
Long-term archiving on: : Friday, November 25, 2011 - 11:21:23 AM

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Florence Poncet, Françoise Valdivieso, Raymonde Gibert, Michèle Pijolat. In situ infrared spectroscopic study of uranium oxides during UO3 carboreduction. Eurosolid 4 : European conference on transformation kinetics and reactivity of solids, Sep 1997, Saint Vincent, Italy. pp.151-157. ⟨emse-00614946⟩

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