The influence of hydration of uranium trioxide on its following reduction by hydrogen into uranium dioxide UO2 - Mines Saint-Étienne Access content directly
Conference Papers Year : 2007

The influence of hydration of uranium trioxide on its following reduction by hydrogen into uranium dioxide UO2

Abstract

The reduction of UO3 by hydrogen has been studied by thermogravimetry in the range 510-600°C and 1-40 kPa. The kinetic curves have been interpreted by a new model involving the steps of nucleation and growth. This allowed to determine the variations of the frequency of nucleation and of the specific rate of growth as a function of hydrogen pressure and temperature. The influence on the kinetics of the hydration of UO3 prior to its reduction by hydrogen could also be explained due to the same model.
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Dates and versions

emse-00614959 , version 1 (17-08-2011)

Identifiers

  • HAL Id : emse-00614959 , version 1

Cite

Catherine Brun, Michèle Pijolat, Michel Soustelle, Françoise Valdivieso. The influence of hydration of uranium trioxide on its following reduction by hydrogen into uranium dioxide UO2. Eurosolid 4 : European conference on transformation kinetics and reactivity of solids, Sep 1997, Saint Vincent, Italy. pp.75-80. ⟨emse-00614959⟩
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