La thermodynamique des hydrates cristallins : stoechiométrie. // The thermodynamic of solid hydrates: stoichiometry.

Abstract : The thermodynamic properties of the divariant equilibra between solid hydrates and water vapour are studied with three models : Polanyi's model, the solid solutions model and the structure elements model. The third model generalizes the first and the second. Relations between the equations of isotherms and some properties of water molecules in the solid (mobility, interactions, associations) are established. The problem of the limits of divariant spaces is studied by the third model treatment.
Type de document :
Article dans une revue
Séminaires de Chimie de l'Etat Solide, 1972, 6, pp.32-50
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https://hal-emse.ccsd.cnrs.fr/emse-00493700
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Soumis le : lundi 21 juin 2010 - 10:00:50
Dernière modification le : mercredi 29 novembre 2017 - 10:07:57

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  • HAL Id : emse-00493700, version 1

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Michel Soustelle, Jean-Jacques Gardet, Bernard Guilhot. La thermodynamique des hydrates cristallins : stoechiométrie. // The thermodynamic of solid hydrates: stoichiometry.. Séminaires de Chimie de l'Etat Solide, 1972, 6, pp.32-50. 〈emse-00493700〉

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