La thermodynamique des hydrates cristallins : stoechiométrie. // The thermodynamic of solid hydrates: stoichiometry. - Mines Saint-Étienne
Article Dans Une Revue Séminaires de Chimie de l'Etat Solide Année : 1972

La thermodynamique des hydrates cristallins : stoechiométrie. // The thermodynamic of solid hydrates: stoichiometry.

Résumé

The thermodynamic properties of the divariant equilibra between solid hydrates and water vapour are studied with three models : Polanyi's model, the solid solutions model and the structure elements model. The third model generalizes the first and the second. Relations between the equations of isotherms and some properties of water molecules in the solid (mobility, interactions, associations) are established. The problem of the limits of divariant spaces is studied by the third model treatment.
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emse-00493700 , version 1 (21-06-2010)

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  • HAL Id : emse-00493700 , version 1

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Michel Soustelle, Jean-Jacques Gardet, Bernard Guilhot. La thermodynamique des hydrates cristallins : stoechiométrie. // The thermodynamic of solid hydrates: stoichiometry.. Séminaires de Chimie de l'Etat Solide, 1972, 6, pp.32-50. ⟨emse-00493700⟩
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