Secondary nucleation of potassium dihydrogen phosphate (KDP): Interest of a turbidimetric study

Philippe Triboulet 1, 2 Michel Cournil 1, 2 George Martin Crawley 1, 2
1 SPIN-ENSMSE - Centre Sciences des Processus Industriels et Naturels
2 GENERIC-ENSMSE - Département Géochimie, environnement, écoulement, réacteurs industriels et cristallisation
Abstract : Secondary nucleation of potassium dihydrogen phosphate (KDP) is studied from electrical conductometry and turbidimetry experiments. Different possible mechanisms are investigated: initial breeding is observed even in the absence of stirring; production of nuclei by collisions with the reactor walls (contact nucleation) is studied in a liquid medium in which KDP is not soluble so that effects other than hydrodynamical/mechanical phenomena are eliminated. Similarities between secondary and heterogenous nucleation could indicate the existence of a mechanism of surface nucleation in addition to the other two effects. Turbidimetry is particularly useful for the quantitative study of the dynamics of secondary nucleation: in this work, it is applied to the study of the inhibition of nuclei production by dissolved aluminium ions. An estimation of the size of the secondary nuclei is calculated from turbidity data.
Type de document :
Article dans une revue
Powder Technology, Elsevier, 1992, 73 (3), pp.195-202. 〈10.1016/0032-5910(92)85026-R〉
Liste complète des métadonnées
https://hal-emse.ccsd.cnrs.fr/emse-00502731
Contributeur : Andrée-Aimée Toucas <>
Soumis le : jeudi 15 juillet 2010 - 15:34:22
Dernière modification le : mercredi 3 août 2016 - 01:01:01

Lien texte intégral

istex

Identifiants

Collections

EMSE | SPIN-ENSMSE | GENERIC-ENSMSE

Citation

Philippe Triboulet, Michel Cournil, George Martin Crawley. Secondary nucleation of potassium dihydrogen phosphate (KDP): Interest of a turbidimetric study. Powder Technology, Elsevier, 1992, 73 (3), pp.195-202. 〈10.1016/0032-5910(92)85026-R〉. 〈emse-00502731〉

Exporter

BibTeX TEI DC DCterms EndNote

Partager

Métriques

Consultations de la notice

95

Contact

support.ccsd.cnrs.fr
hal.support@ccsd.cnrs.fr
Logo CCSD