Preparation and electrical properties of a pyrochlore-related Ce2Zr2O8−x phase

Abstract : A pyrochlore-related Ce2Zr2O8−x phase has been prepared in a reduction reoxidation process from Ce0.5Zr0.5O2 powders. Ce2Zr2O8−x, based on a cubic symmetry with a=1.053 nm, decomposes in nitrogen at 800 °C, but remains stable up to 900 °C in air. It shows mixed oxygen ionic and electronic conductivity. The bulk conductivity at 700 °C is 4×10−4 S cm−1 in air and 1×10−2 S cm−1 in nitrogen, and the activation energy is 1.27 eV in air. In nitrogen, the Arrhenius law is not obeyed, and a curved plot was obtained from 400 to 700 °C; then, the conductivity decreased rapidly due to the thermal decomposition of Ce2Zr2O8−x.
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Solid State Ionics, Elsevier, 2003, 160 (3-4), pp.317-326. 〈10.1016/S0167-2738(03)00207-8〉
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https://hal-emse.ccsd.cnrs.fr/emse-00609089
Contributeur : Andrée-Aimée Toucas <>
Soumis le : lundi 18 juillet 2011 - 10:34:14
Dernière modification le : jeudi 11 janvier 2018 - 06:21:23

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Hui Zhao, Nicolas Guillet, Françoise Valdivieso, Michèle Pijolat. Preparation and electrical properties of a pyrochlore-related Ce2Zr2O8−x phase. Solid State Ionics, Elsevier, 2003, 160 (3-4), pp.317-326. 〈10.1016/S0167-2738(03)00207-8〉. 〈emse-00609089〉

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